Polyfunctionalized macrocycles demonstrate enantioselective and ditopic binding properties.
نویسندگان
چکیده
A pair of enantioselective, ditopic macrocycles is described; the receptors bind chiral ammonium cations in a manner that depends on the stereochemistry of the cation as well as the nature of its counter anion.
منابع مشابه
Design and synthesis of chiral macrocycles as receptors for enantioselective molecular recognition and as catalysts for asymmetric reactions
The design and the synthesis of chiral macrocycles acting as enantioselective receptors is of great interest in the field of enzyme mimicking enantioselective catalysis as well as in that of racemic resolution and of chiral sensing. Recently particular attention has been devoted to neutral ditopic receptors able to simultaneously bind chiral ammonium cations and their counteranions. In this wor...
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عنوان ژورنال:
- Chemical communications
دوره 26 شماره
صفحات -
تاریخ انتشار 2005